10563-09-4

Basic information

• Product Name: 3-endo-chloro-2-exo-phenylthiobicyclo[2.2.1]heptane
• CAS NO: 10563-09-4
• Molecular Weight: 238.781
• Mol File: 10563-09-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3-endo-chloro-2-exo-phenylthiobicyclo[2.2.1]heptane(CAS DataBase Reference)
• NIST Chemistry Reference: 3-endo-chloro-2-exo-phenylthiobicyclo[2.2.1]heptane(10563-09-4)
• EPA Substance Registry System: 3-endo-chloro-2-exo-phenylthiobicyclo[2.2.1]heptane(10563-09-4)

Safety Data

• Hazardous Substances Data: 10563-09-4(Hazardous Substances Data)

Upstream product

• 498-66-8 norborn-2-ene 
• 54815-45-1 ethyl benzenesulfenate 
• 931-59-9 benzenesulfenyl chloride 

Relevant articles and documents

Halo(trimethyl)silanes as activating coreagents in sulfenylation of olefins [1]

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A new method for the activation of ethyl benzenesulfenate in electrophilic addition reactions

Reactions of unsaturated compounds with the PhSOEt-SOHal2 and PhSOEt-Me3SiHal systems (Hal = Cl or Br) were proposed as a new route to haloalkyl phenyl sulfides. With acyclic and mono- and bicyclic alkenes and dienes as examples, the

Elimination and Addition Reactions. Part 37. A Comparative Study of Electronic, Steric , and Solvent Effects upon Reactivity in Additions of Benzenesulphenyl Chloride to Alkenes

Rates of additions of benzenesulphenyl chloride to 35 alkenes in several solvents have been measured, and the products of the reactions have in most cases been identified.Results for arylalkenes broadly confirm previous work, but the responses to solvent change are not uniform throughout.The reactivity of bridged cycloalkanes is substantially greater than that of cycloalkenes, but that of cyclo-pentadiene dimer is anomalously small.For allylic substrates, the correlation of electron density at the double bond with reactivity is shown by a rectilinear relationship between log k and ?I.Allyl iodide and allyl alcohol are anomalously more reactive than this correlation would predict; this is accounted for by solvation and by internal solvation effects respectively.