10566-32-2

Basic information

• Product Name: 9,10-Anthracenedione, 2-iodo-
• CAS NO: 10566-32-2
• Molecular Formula: C14H7IO2
• Molecular Weight: 334.113
• Mol File: 10566-32-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 9,10-Anthracenedione, 2-iodo-(CAS DataBase Reference)
• NIST Chemistry Reference: 9,10-Anthracenedione, 2-iodo-(10566-32-2)
• EPA Substance Registry System: 9,10-Anthracenedione, 2-iodo-(10566-32-2)

Safety Data

• Hazardous Substances Data: 10566-32-2(Hazardous Substances Data)

Upstream product

• 90-44-8 anthracen-9(10H)-one 

Downstream Products

• 13388-33-5 2-vinylanthracene-9,10-dione 
• 1449478-95-8 2-[(4-methoxyphenyl) ethynyl]-9,10-bis(trifluoromethyl)anthracene 
• 1449478-92-5 C₂₃H₁₁F₉ 
• 1449478-91-4 C₂₃H₁₄F₆O 
• 1449478-90-3 C₂₂H₁₂F₆ 
• 6485-97-8 2-Phenyl-anthrachinon 
• 1981-38-0 2-phenylanthracene 
• 936735-91-0 C₆H₄(CO)2C₆H₃(C₂C₆H₄)3(C₆H₃(C(CH₃)3)2)3ZnC₂₀H₈N₄ 
• 936735-91-0 C₁₀₀H₉₀N₄O₂Zn 
• 1032401-47-0 2-{[4-(dimethylamino)phenyl]ethynyl}anthracene-9,10-dione 
• 1032401-46-9 2-[4-(dimethylamino)phenyl]anthracene-9,10-dione 
• 736998-56-4 2-vinyl-9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene 
• 868383-09-9 5'-O-dimethoxytrityl-8-[(anthraquinon-2-yl)ethynyl]-2'-deoxyadenosine 3'-dibenzyl phosphate 
• 868383-10-2 8-[(anthraquinon-2-yl)ethynyl]-2'-deoxyadenosine 3'-dibenzyl phosphate 

Relevant articles and documents

Reactions of Aryl Ketones and Coumarins with Iodine(III) Tris(trifluoroacetate)

The reaction of acetophenones with iodine(III) tris(trifluoroacetate) yields 3'- and/or 2-iodo derivatives, depending upon the substituent on the aromatic ring and the reaction conditions.The reaction was examinedby changing the molar ratio of acetophenone versus the reagent, reaction temperature, and solvent.In similar reactions flavanones and coumarins gave iodo derivatives in which iodine is incorporated at various positions orientated by the oxygen functions. 1,2-Diphenylethanone yields 2-hydroxy-2-(2-iodophenyl)-1-phenylethanone and 1-(2-iodophenyl)-2-phenylethanedione.The reactions of other aromatic ketones such as 9-xanthenone, 9-fluorenone, and anthrone also give iodo derivatives in moderate to good yields.The mechanisms for the iodination at the α-carbon to the carbonyl group have been discussed.