105817-90-1

Basic information

• Product Name: 1-<<2-(Trifluormethylsulfonyloxy)-1-cyclohexen-1-yl>methylen>-piperidinium-trifluormethansulfonat
• CAS NO: 105817-90-1
• Molecular Weight: 475.43
• Mol File: 105817-90-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-<<2-(Trifluormethylsulfonyloxy)-1-cyclohexen-1-yl>methylen>-piperidinium-trifluormethansulfonat(CAS DataBase Reference)
• NIST Chemistry Reference: 1-<<2-(Trifluormethylsulfonyloxy)-1-cyclohexen-1-yl>methylen>-piperidinium-trifluormethansulfonat(105817-90-1)
• EPA Substance Registry System: 1-<<2-(Trifluormethylsulfonyloxy)-1-cyclohexen-1-yl>methylen>-piperidinium-trifluormethansulfonat(105817-90-1)

Safety Data

• Hazardous Substances Data: 105817-90-1(Hazardous Substances Data)

Upstream product

• 6135-20-2 2-(Piperidinomethylen)-1-cyclohexanon 
• 358-23-6 trifluoromethylsulfonic anhydride 

Relevant articles and documents

Dication Ethers, 12. - Reaction of Enaminones with Triflic Anhydride: 3-Trifloxypropeniminium- and Bis(3-amino-2-propenylio) Ether Salts

Reaction of enaminones 1 a-n with triflic anhydride (Tf2O) in a 1:1 molar ratio yields 3-trifloxypropeniminium triflates 2 a-n by O-sulfonylation.With a 2:1 molar ratio, the bis(3-amino-2-propenylio) ether bistriflates 3 are obtained.The configuration of the cations of 2 and 3 is derived from 1H and 13C NMR data as far as possible.Hydrolysis of the ambifunctional salts 3 may occur either at the iminium or the vinyl ether functions.