105827-62-1

Basic information

• Product Name: 3,5-Dioxa-2,6-disilaheptane, 2,2,6,6-tetramethyl-4-(4-methyl-2-methylene-3-cyclohexen-1-ylidene)-
• CAS NO: 105827-62-1
• Molecular Formula: C15H28O2Si2
• Molecular Weight: 296.557
• Mol File: 105827-62-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3,5-Dioxa-2,6-disilaheptane, 2,2,6,6-tetramethyl-4-(4-methyl-2-methylene-3-cyclohexen-1-ylidene)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-Dioxa-2,6-disilaheptane, 2,2,6,6-tetramethyl-4-(4-methyl-2-methylene-3-cyclohexen-1-ylidene)-(105827-62-1)
• EPA Substance Registry System: 3,5-Dioxa-2,6-disilaheptane, 2,2,6,6-tetramethyl-4-(4-methyl-2-methylene-3-cyclohexen-1-ylidene)-(105827-62-1)

Safety Data

• Hazardous Substances Data: 105827-62-1(Hazardous Substances Data)

Upstream product

• 30021-64-8 ethyl 2,6-dimethyl-1,3-cyclohexadiene-1-carboxylate 
• 75-77-4 chloro-trimethyl-silane 
• 105827-63-2 2,6-dimethyl-1,3-cyclohexadiene-1-carboxylic acid 

Downstream Products

• 71582-54-2 (+)-nogarene 

Relevant articles and documents

TOTAL SYNTHESES OF (+)-NOGARENE AND (+)-7,8-DIHYDRONOGARENE

Total syntheses of the title compounds, the simplest and the hitherto unknown novel nogalamycin congeners, were first accomplished by elaborating the CDEF-ring system (5) from the methyl ketone (6) and subjecting 5 to regioselective Diels-Alder reaction with the bistrimethylsilyl keteneacetal (22).