105873-95-8Relevant articles and documents
1,1-Bis(benzotriazolyl) derivatives as gem-dianion synthons
Katritzky, Alan R.,Fali, Clara N.,Qi, Ming
, p. 2289 - 2292 (1998)
Bis(benzotriazolyl)methylbenzenes 1a,b were converted by excess lithium metal in the presence of ketones into the 1,3-diols 3a-g in moderate to good yields. However, similar treatment of 5 gave only the mono reduction products 6, 7. Compounds 1a,b reacted
Novel tele nucleophilic aromatic substitutions in α-(benzotriazol-1-yl)alkyl aryl ketones
Katritzky, Alan R.,Wu, Hong,Xie, Linghong
, p. 903 - 906 (2007/10/03)
Reactions of α-(benzoltriazol-1-yl)alkyl aryl ketones 2 with alkyllithiums or Grignard reagents afforded para-alkylated products 5 via novel tele nucleophilic, aromatic substitutions.
The Chemistry of N-Substituted Benzotriazoles. Part 5. Reactions of Benzotriazole with Aldehydes and Thionyl Chloride-Formation of (Benzotriazol-1-yl)-1-chloroalkanes and Bis(benzotriazolyl)alkanes
Katritzky, Alan R.,Kuzmierkiewicz, Wojciech,Rachwal, Bogumila,Rachwal, Stanislaw,Thomson, Julie
, p. 811 - 818 (2007/10/02)
Reaction of benzotriazole with an excess of aliphatic aldehydes and thionyl chloride in refluxing chloroform gives the corresponding 1-(benzotriazol-1-yl)-1-chloroalkanes.Products with an α-hydrogen next to the chlorine-bearing carbon atom gradually elimi