105996-73-4

Basic information

• Product Name: (1S,3S)-(+)-2,2-dimethyl-6-methylene-3-tosyloxycyclohexanemethyl formate
• Synonyms: (1S,3S)-(+)-2,2-dimethyl-6-methylene-3-tosyloxycyclohexanemethyl formate
• CAS NO: 105996-73-4
• Molecular Weight: 352.452
• Mol File: 105996-73-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,3S)-(+)-2,2-dimethyl-6-methylene-3-tosyloxycyclohexanemethyl formate(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,3S)-(+)-2,2-dimethyl-6-methylene-3-tosyloxycyclohexanemethyl formate(105996-73-4)
• EPA Substance Registry System: (1S,3S)-(+)-2,2-dimethyl-6-methylene-3-tosyloxycyclohexanemethyl formate(105996-73-4)

Safety Data

• Hazardous Substances Data: 105996-73-4(Hazardous Substances Data)

Upstream product

• 105996-61-0 (3S)-6-formyl-2,2-dimethyl-3-tetrahydropyranyloxycyclohexanone 
• 105996-65-4 (S)-(-)-3,3-dimethyl-4-tetrahydropyranyloxy-1-cyclohexenecarbaldehyde 
• 105996-69-8 (1S,3S)-(+)-2,2-dimethyl-6-methylene-3-tetrahydropyranyloxycyclohexanemethanol 
• 105996-62-1 (S)-6-[1-Butylsulfanyl-meth-(E)-ylidene]-3-hydroxy-2,2-dimethyl-cyclohexanone 
• 562-13-0 2,2-dimethyl-1,3-cyclohexanedione 
• 3495-36-1 cesium formate 
• 105996-72-3 (+)-(1S,3S)-(2,2-dimethyl-6-methylene-3-p-toluenesulfonyloxycyclohexyl)methyl p-toluenesulfonate 
• 105996-64-3 (3S)-6-butylthiomethylene-2,2-dimethyl-3-tetrahydropyranyloxycyclohexan-1-ol 
• 87655-21-8 (S)-3-hydroxy-2,2-dimethylcyclohexanone 
• 98-59-9 p-toluenesulfonyl chloride 
• 104435-19-0 (S)-(-)-3,3-dimethyl-4-tetrahydropyranyloxy-1-cyclohexanemethanol 
• 103634-03-3 (S)-(+)-2,2-dimethyl-3-tetrahydropyranyloxycyclohexanone 
• 105996-71-2 (-)-(1S,3S)-(3-hydroxy-2,2-dimethyl-6-methylenecyclohexyl)methyl p-toluenesulfonate 
• 105996-63-2 (S)-(-)-6-n-butylthiomethylene-2,2-dimethyl-3-tetrahydropyranyloxycyclohexanone 

Relevant articles and documents

SHYNTHESIS OF (1S,5R)-KARAHANA ETHER AND (1S,5R)-KARAHANA LACTONE. THE OPTICALLY ACTIVE FORMS OF UNIQUE MONOTERPENES WITH A 6-OXABICYCLOOCTANE RING SYSTEM

(1S,5R)-(-)-Karahana ether (8,8-dimethyl-2-methylene-6-oxabicyclooctane) and (1S,5R)-(-)-karahana lactone (8,8-dimethyl-2-methylene-6-oxabicyclooctan-7-one) were synthesized from (S)-3-hydroxy-2,2-dimethylcyclohexanone.The natural karahana lactone was shown to be almost racemic (ca. 1.3 percent e.e.).