106109-15-3

Basic information

• Product Name: [Pd((C₅H₄N)(C₆H₅)2CH)2(CH₃COO)2]
• CAS NO: 106109-15-3
• Molecular Weight: 715.157
• Mol File: 106109-15-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd((C₅H₄N)(C₆H₅)2CH)2(CH₃COO)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd((C₅H₄N)(C₆H₅)2CH)2(CH₃COO)2](106109-15-3)
• EPA Substance Registry System: [Pd((C₅H₄N)(C₆H₅)2CH)2(CH₃COO)2](106109-15-3)

Safety Data

• Hazardous Substances Data: 106109-15-3(Hazardous Substances Data)

Upstream product

• 3678-70-4 Diphenyl-2-pyridylmethan 
• 3375-31-3 palladium diacetate 

Relevant articles and documents

Interaction of Palladium(II) Acetate with Substituted Pyridines, including a Cyclometallation Reaction and the Structure of 2-C5H3N>(O2CMe)>*3H2O

The reactivity of meso- and rac- diastereoisomers of 2,6-bispyridine 2C5H3N>,2,6-bispyridine 2C5H3N>, and the pyridin-2-yl methanes (py)nPh3-nCH (n = 1-3), (py)nCH4-n (n = 2 or 3), and (py)3PhC toward palladium(II) acetate in refluxing glacial acetic acid and at ambient temperature in organic solvents has been investigated.The nitrogen donor ligands form co-ordination derivatives in organic solvents.All except α-phenyl-α-(pyridin-2-yl)toluene form identical complexes in glacial acetic acid, with (py)Ph2CH undergoing cyclometallation to form (μ-O2CMe)>2>.meso-2C5H3N, which binds as a tripodal tridentate ligand to methylmercury(II), has been shown by a single crystal X-ray study to act as a planar tridentate ligand to palladium(II) in 2C5H3N>(O2CMe)>*3H2O with square-planar co-ordination being completed by a unidentate acetate group 1/c, a = 11.795(5), b = 23.10(1), c = 12.313(5) Angstroem, β = 95.64(3)deg, Z = 4; R = 0.051 for 3 657 'observed' reflections>.Syntheses of the new ligand 2C5H3N, with five pyridine donor groups, and α,α,α,-tris(pyridin-2-yl)toluene are described.