106367-82-2

Basic information

• Product Name: 3,3-dichloro-1,2-dehydroaspidospermidin-8-one
• Synonyms: 3,3-dichloro-1,2-dehydroaspidospermidin-8-one
• CAS NO: 106367-82-2
• Molecular Weight: 363.287
• Mol File: 106367-82-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3,3-dichloro-1,2-dehydroaspidospermidin-8-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3-dichloro-1,2-dehydroaspidospermidin-8-one(106367-82-2)
• EPA Substance Registry System: 3,3-dichloro-1,2-dehydroaspidospermidin-8-one(106367-82-2)

Safety Data

• Hazardous Substances Data: 106367-82-2(Hazardous Substances Data)

Upstream product

• 80664-35-3 (+/-)-2,3-didehydro-1-<(p-methoxyphenyl)sulfonyl>aspidospermidin-8-one 

Downstream Products

• 473-99-4 14,15-dihydroeburnamenin-14-ol 

Relevant articles and documents

METHODS FOR INDOLE ALKALOID SYNTHESIS: REACTIONS OF N-ARYLSULFONYLENAMINES WITH ELECTROPHILES. AN EXPEDITIOUS SYNTHESIS OF (+/-)-EBURNAMONINE.

Treatment of 4 with MCPBA gave 9.The pentacyclic amide 3 on exposure to cyanogen chloride gave the cis-chloro-hydrin 20, and the geminal dichloride 21.When 21 was treated with HCl/MeOH it rapidly rearranged to eburnamonine lactam 22.