106851-31-4

Basic information

• Product Name: 6-Phenyl-1H-indole
• Synonyms: 6-Phenyl-1H-indole;6-Phenylindole
• CAS NO: 106851-31-4
• Molecular Formula: C₁₄H₁₁N
• Molecular Weight: 193.24384
• Mol File: 106851-31-4.mol
• Article Data: 19

Chemical Properties

• Melting Point: 160-161℃ (acetone )
• Appearance: /
• CAS DataBase Reference: 6-Phenyl-1H-indole(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Phenyl-1H-indole(106851-31-4)
• EPA Substance Registry System: 6-Phenyl-1H-indole(106851-31-4)

Safety Data

• Hazardous Substances Data: 106851-31-4(Hazardous Substances Data)

Upstream product

• 17422-33-2 6-chloroindole 
• 98-80-6 phenylboronic acid 
• 104-54-1 3-Phenylpropenol 
• 221006-77-5 cinnamylboronic acid 
• 1449115-30-3 6-phenyl-1-tosyl-1H-indole 
• 52415-29-9 6-bromo-1H-indole 
• 106851-24-5 4-(2,2-Dimethoxy-ethyl)-3-nitro-biphenyl 
• 106851-19-8 Trimethyl-(3-nitro-biphenyl-4-ylethynyl)-silane 
• 679794-03-7 1‐(benzenesulfonyl)‐6‐bromo‐1H‐indole 
• 106851-29-0 4-(2,2-Dimethoxy-ethyl)-biphenyl-3-ylamine 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 

Downstream Products

• 1210793-56-8 1,2-di(6-phenyl-1-indolyl)benzene 

Relevant articles and documents

Lewis Acid Catalyzed Enantioselective Desymmetrization of Donor–Acceptor meso-Diaminocyclopropanes

The first Lewis acid catalyzed enantioselective ring-opening desymmetrization of a donor–acceptor meso-diaminocyclopropane is reported. The copper(II)-catalyzed Friedel–Crafts alkylation of indoles and one pyrrole with an unprecedented meso-diaminocyclopropane delivered enantioenriched, diastereomerically pure urea products, which are structurally related to natural and synthetic bioactive compounds. The development of a new ligand through the investigation of an underexplored subclass of bis(oxazoline) ligands was essential for achieving high enantioselectivities.

A one-pot "back-to-front" approach for the synthesis of benzene ring substituted indoles using allylboronic acids

Synthesis of only benzene ring functionalized indoles and poly-substituted carbazoles is reported via a one-pot triple cascade benzannulation protocol. Usage of differently substituted and readily accessible allylboronic acids as a 3-carbon annulating partner enables diverse aliphatic and aromatic substitution patterns, which is still a daunting task. This scalable synthetic protocol tolerates broad scope, thus enabling further downstream modifications. As an application, carbazole based natural products glycozoline and glycozolinol were synthesized. This journal is

Synthesis of Enaminone-Pd(II) Complexes and Their Application in Catalysing Aqueous Suzuki-Miyaura Cross Coupling Reaction

A series of Pd(II)-enaminone complexes, termed Pd(eao)2, have been synthesized and characterized. The investigation on the catalytic activities of these new Pd(II)-reagents has proved that the Pd(eao)2-1 possesses excellent catalytic activity for the Suzuki- Miyaura cross coupling reactions of aryl bromides/chlorides with aryl/vinyl boronic acids in the environmentally benign media of aqueous PEG400 at low loading (5 mol‰). The superiority of this Pd(II)-reagent to those commercial Pd(II) and Pd(0) catalysts in catalyzing the reactions has been confirmed by parallel experiments. What's more, Pd(eao)2-2 has been found as a practical catalyst for the homo-coupling reactions of aryl boronic acids.