106914-54-9Relevant articles and documents
A Facile Method for the Oxidation of Aldehydes to Carboxylic Acids via Acetal-type Diperoxides
Mukaiyama, Teruaki,Miyoshi, Norikazu,Kato, Jun-ichi,Ohshima, Masahiro
, p. 1385 - 1388 (1986)
In the presence of a catalytic amount of trityl perchlorate, aldehydes smoothly react with t-butyl trimethylsilyl peroxide to give the acetal-type diperoxides in good yields.Treatment of these diperoxides with piperidine at 90 degC or the aqueous solution of CuSO4 and L-ascorbic acid at room temperature gave the corresponding carboxylic acids in good yields.