106943-90-2

Basic information

• Product Name: 3-Thiophenamine, N-(phenylmethyl)-
• CAS NO: 106943-90-2
• Molecular Formula: C11H11NS
• Molecular Weight: 189.281
• Mol File: 106943-90-2.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: 3-Thiophenamine, N-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Thiophenamine, N-(phenylmethyl)-(106943-90-2)
• EPA Substance Registry System: 3-Thiophenamine, N-(phenylmethyl)-(106943-90-2)

Safety Data

• Hazardous Substances Data: 106943-90-2(Hazardous Substances Data)

Upstream product

• 6165-69-1 Thien-3-ylboronic acid 
• 622-30-0 N-benzyl hydroxylalmine 
• 10486-61-0 3-thienyl iodide 
• 100-46-9 benzylamine 
• 872-31-1 3-Bromothiophene 
• 17721-06-1 3-aminothiophene 
• 100-52-7 benzaldehyde 
• 79128-75-9 N-Thiophen-3-yl-benzamide 

Downstream Products

• 1147124-44-4 C₂₆H₁₈N₂O₂S₂ 
• 1147124-42-2 C₁₃H₉NO₂S 
• 106943-98-0 3-(N-benzyl-N-methylamino)thiophen 
• 106943-97-9 N-benzyl N-thienyl-3 formamide 

Relevant articles and documents

Copper(i)-catalysed intramolecular hydroarylation-redox cross-dehydrogenative coupling ofN-propargylanilines with phosphites

Intramolecular hydroarylation-redox cross-dehydrogenative coupling ofN-propargylanilines with phosphite diesters proceeded in the presence of Cu(i)-catalysts (20 mol%) to selectively give 2-phosphono-1,2,3,4-tetrahydroquinolines in good yields with 100% atomic utilization. P-H and two C-H bonds are activated at once and these hydrogen atoms are trapped by a propargylic triple bond in the molecule.

Oxalic amide ligands, and uses thereof in copper-catalyzed coupling reaction of aryl halides

The present invention provides oxalic amide ligands and uses thereof in copper-catalyzed coupling reaction of aryl halides. Specifically, the present invention provides a use of a compound represented by formula I, wherein definitions of each group are described in the specification. The compound represented by formula I can be used as a ligand in copper-catalyzed coupling reaction of aryl halides for the formation of C—N, C—O and C—S bonds.

An Effective Heterogeneous Copper Catalyst System for C-N Coupling and Its Application in the Preparation of 2-Methyl-4-methoxydiphenylamine (MMDPA)

A ligand-recyclable, environmentally benign heterogeneous catalyst system composed of CuI and polystyrene-supported N (-(4-(aminomethyl)naphthalen-1-yl)- N (-phenyl-1 H -pyrrole-2-carbohydrazide (PSAP) has been established for Ullmann type C-N coupling based on the homogeneous catalyst system N ′, N ′-diphenyl-1 H -pyrrole-2-carbohydrazide/CuI. This heterogeneous catalyst system maintained the catalytic effectiveness of the homogeneous catalyst. A variety of functionalized aryl bromides can be efficiently aminated with aryl amines and aliphatic amines with high selectivity for amines over alcohols. Moreover, a practical application of this catalyst system to promote the reaction of commercially available 4-methoxy-2-methylaniline and bromobenzene in 10 mmol scale, provided 2-methyl-4-methoxydiphenylamine (MMDPA) with 93% yield with the merit of the approach being simple operation for work-up and purification.