107002-87-9

Basic information

• Product Name: C₆H₅C₂H₅NCOOCH₃
• Synonyms: C₆H₅C₂H₅NCOOCH₃
• CAS NO: 107002-87-9
• Molecular Weight: 179.219
• Mol File: 107002-87-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₆H₅C₂H₅NCOOCH₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₆H₅C₂H₅NCOOCH₃(107002-87-9)
• EPA Substance Registry System: C₆H₅C₂H₅NCOOCH₃(107002-87-9)

Safety Data

• Hazardous Substances Data: 107002-87-9(Hazardous Substances Data)

Upstream product

• 19433-17-1 acetophenone O-acetyloxime 
• 19433-17-1 (E)‐1‐phenylethan‐1‐one O‐acetyl oxime 

Relevant articles and documents

Highly enantioselective Pd-catalyzed asymmetric hydrogenation of activated imines

(Chemical Equation Presented) Pd/bisphosphines complexes are highly effective catalysts for asymmetric hydrogenation of activated imines in trifluoroethanol. The asymmetric hydrogenation of N-diphenylphosphinyl ketimines 3 with Pd(CF3CO2)/(S)-SegPhos indicated 87-99% ee, and N-tosylimines 5 could gave 88-97% ee with Pd-(CF3CO 2)/(S)-SynPhos as a catalyst. Cyclic N-sulfonylimines 7 and 11 were hydrogenated to afford the useful chiral sultam derivatives in 79-93% ee, which are important organic synthetic intermediates and structural units of agricultural and pharmaceutical agents.

REDUCTION OF OXIMES WITH HYDROSILANE/H(1+) REAGENT

Hydrosilane/H+ reagent reduced oximes in good yields.Stereospecific reduction of (2-acetoxy-1-phenylpropylidene) benzyloxyazane (3) was observed; the (E)-isomer gave erythro-1-phenyl-1-benzyloxyamino-2-propanol (4) in 99percent selectivity, whe