107046-99-1Relevant articles and documents
REACTIONS OF AROMATIC NITRO COMPOUNDS. LXIV. ANIONIC ? COMPLEXES OF THE ALKYL ETHERS OF 2,4,6-TRINITROPHENOL WITH THE ALCOHOLATES OF DIHYDRIC AND TRIHYDRIC ALCOHOLS
Mel'nikov, A. I.,Gitis, S. S.,Kaminskii, A. Ya.
, p. 268 - 274 (2007/10/02)
Sodium 1-methoxy-1-(β-hydroxypropoxy)-2,4,6-trinitro-2,5-cyclohexadienide was obtained from 2,4,6-trinitroanisole and sodium 2-hydroxypropoxide.It was then converted into corresponding spirocyclic anionic ? complex.In the reaction of 2,4,6-trinitrophenetole with sodium 2-hydroxyethoxide, 3-hydroxypropoxide, and 4-hydroxybutoxide the 1-ethoxy-1-hydroxyalkoxyl ? complexes are formed at the first stage and are then converted into spirocyclic and 1,1-dihydroxyalkoxyl ? complexes.Spirocyclization only takes place in the presence of the β-hydroxy group.The transformations are realized with the participation of the glycol ethers of 2,4,6-trinitrophenol, which are formed in the reaction as transetherification products.