107096-52-6Relevant articles and documents
Selective Electrochemical Oxygenation of Alkylarenes to Carbonyls
Li, Xue,Bai, Fang,Liu, Chaogan,Ma, Xiaowei,Gu, Chengzhi,Dai, Bin
supporting information, p. 7445 - 7449 (2021/10/02)
An efficient electrochemical method for benzylic C(sp3)-H bond oxidation has been developed. A variety of methylarenes, methylheteroarenes, and benzylic (hetero)methylenes could be converted into the desired aryl aldehydes and aryl ketones in moderate to excellent yields in an undivided cell, using O2 as the oxygen source and lutidinium perchlorate as an electrolyte. On the basis of cyclic voltammetry studies, 18O labeling experiments, and radical trapping experiments, a possible single-electron transfer mechanism has been proposed for the electrooxidation reaction.
Selective Palladium(II)-Catalyzed Carbonylation of Methylene β-C?H Bonds in Aliphatic Amines
Cabrera-Pardo, Jaime R.,Trowbridge, Aaron,Nappi, Manuel,Ozaki, Kyohei,Gaunt, Matthew J.
supporting information, p. 11958 - 11962 (2017/09/20)
Palladium(II)-catalyzed C?H carbonylation reactions of methylene C?H bonds in secondary aliphatic amines lead to the formation of trans-disubstituted β-lactams in excellent yields and selectivities. The generality of the C?H carbonylation process is aided by the action of xantphos-based ligands and is important in securing good yields for the β-lactam products.
Synthesis and computational analysis of densely functionalized triazoles using o -nitrophenylalkynes
McIntosh, Melissa L.,Johnston, Ryne C.,Pattawong, Ommidala,Ashburn, Bradley O.,Naffziger, Michael R.,Cheong, Paul Ha-Yeon,Carter, Rich G.
, p. 1101 - 1112 (2012/03/11)
Dipolar cylcoadditions with azides using a series of o-nitrophenylethynes and disubstituted alkynes were studied experimentally and computationally. Density functional theory computations reveal the steric and electronic parameters that control the regios
