107146-03-2Relevant articles and documents
THE INVENTION OF NEW RADICAL CHAIN REACTIONS. PART XIII. GENERATION AND REACTIVITY OF PERFLUOROALKYL RADICALS FROM THIOHYDROXAMIC ESTERS
Barton, Derek H. R.,Lacher, Brigitte,Zard, Samir Z.
, p. 2325 - 2328 (2007/10/02)
The perfluoro acid esters of N-hydroxypyridine 2-thione give perfluoroalkyl radicals on irradiation.Without any trap the radicals participate in a decarboxylative rearrangement to give 2-perfluoroalkylthiopyridines in excellent yield.In the presence of an appropriate trap, such as an electron rich olefin, adducts are formed in variable yield.