107150-81-2Relevant articles and documents
Nucleophilic Catalysis of Glycoside Hydrolysis. The Hydrolysis of 4-Nitrophenyl α- and β-D-glucopyranoside Tetraphosphates
Camilleri, Patrick,Jones, Rosie F. D.,Kirby, Anthony J.,Stroemberg, Roger
, p. 2085 - 2090 (2007/10/02)
The octaanion of the tetraphosphate of 4-nitrophenyl β-D-glucopyranoside is hydrolysed up to 100 times faster than model compounds, in a reaction which is pH-independent above pH 9.The mechanism involves intramolecular nucleophilic catalysis by the phosph