1071821-48-1Relevant articles and documents
CpTiCl2, an Improved Titanocene(III) Catalyst in Organic Synthesis
Roldan-Molina, Esther,Padial, Natalia M.,Lezama, Luis,Oltra, J. Enrique
supporting information, p. 5997 - 6001 (2018/11/23)
Preparation, EPR analysis, and advantages in green organic chemistry of CpTiCl2, an improved single-electron transfer catalyst, are reported. Under mild conditions, this organometallic complex provides excellent yields of homoallylic and homopropargylic alcohols in Barbier-type allylation and propargylation reactions. Moreover, in the presence of a bidentate BOX ligand, Barbier-type cyclization reactions catalyzed by CpTiCl2 can be carried out in an enantioselective manner.