107195-10-8

Basic information

• Product Name: Ethanone, 2-(2-imidazolidinylidene)-1-(4-methoxyphenyl)-
• CAS NO: 107195-10-8
• Molecular Formula: C12H14N2O2
• Molecular Weight: 218.255
• Mol File: 107195-10-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-(2-imidazolidinylidene)-1-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-(2-imidazolidinylidene)-1-(4-methoxyphenyl)-(107195-10-8)
• EPA Substance Registry System: Ethanone, 2-(2-imidazolidinylidene)-1-(4-methoxyphenyl)-(107195-10-8)

Safety Data

• Hazardous Substances Data: 107195-10-8(Hazardous Substances Data)

Upstream product

• 112030-63-4 3-(4-Methoxy-phenyl)-3-oxo-propionimidic acid ethyl ester; hydrochloride 
• 107-15-3 ethylenediamine 
• 33868-76-7 1-(4-methoxyphenyl)-3,3-bis(methylsulfanyl)propenone 
• 3672-47-7 3-oxo-3-(4'-methoxyphenyl)propanenitrile 
• 50849-98-4 3,3-dimercapto-1-(4-methoxy-phenyl)-propenone 

Downstream Products

• 138963-30-1 2-<(2,4-dinitrophenyl)(4-methoxybenzyol)methylene>imidazolidine 
• 1561996-86-8 12-(4-methoxybenzoyl)-9,10-dihydro-6H-chromeno[4,3-d]-imidazo[1,2-a]pyridin-6-one 
• 1561996-95-9 2-bromo-12-(4-methoxybenzoyl)-9,10-dihydro-6H-chrom-eno-[4,3-d]imidazo[1,2-a]pyridin-6-one 
• 1631146-65-0 2-(imidazolidin-2-ylidene)-1-(4-methoxyphenyl)-2-(phenylthio)ethan-1-one 
• 1631146-76-3 2-(imidazolidin-2-ylidene)-1-(4-methoxyphenyl)-2-(phenylselanyl)ethan-1-one 
• 115890-19-2 1,2,3,6-tetrahydro-7-(4-methoxybenzoyl)-5H-pyrrolo<1,2-a>imidazol-5-one 
• 112030-68-9 2-(4,5-Dihydro-1H-imidazol-2-yl)-1-(4-methoxy-phenyl)-ethanone; hydrochloride 
• 132111-54-7 3-(p-methoxyphenyl)-5,6-dihydro-4H-imidazo<1,2-c><1,2,3>triazole 
• 132111-50-3 1,5-bis(p-methoxyphenyl)-4-(2-imidazolinyl)-1,2,3-triazole 
• 115859-61-5 2-<1-(4-methoxybenzoyl)-2-phenylethylidene>imidazolidine 
• 118792-73-7 [7-(4-Methoxy-benzoyl)-5-oxo-2,3,5,6-tetrahydro-1H-pyrrolo[1,2-a]imidazol-6-yl]-acetic acid 

Relevant articles and documents

Multicomponent Tether Catalysis Synthesis of Highly Functionalized 4-(Pyridin-2-ylmethyl)-2-aminopyrroles via Cascade Reaction Is Accompanied by Decarboxylation

A multicomponent tether catalysis protocol for the synthesis of 4-(pyridin-2-ylmethyl)-2-aminopyrroles (PMAPs) was constructed by simply refluxing a mixture of ethyl 2-(pyridin-2-yl)acetates 1 and various types of arylglyoxal monohydrates 2 and different heterocyclic ketene aminals 3 in EtOH solvent. Based on this reaction, a series of highly functionalized PMAPs were obtained through a novel cascade reaction accompanied by a decarboxylation mechanism. As a result, the pyridin-2-ylmethyl was successfully introduced in the target compounds, and a library of PMAPs were easily constructed using the cascade reaction described in this study. This protocol demonstrated that the most important feature was the decarboxylation reaction of the 2-(pyridin-2-yl)acetates 1, which can be used in the synthesis of pyridin-2-ylmethyl-substituted heterocycles, including pyrroles, pyridines, quinolones, and other heterocyclic compounds resembling those found in nature.

Synthesis of imidazo[1,2-a]pyridines and pyrido[1,2-a]pyrimidines in water and their snar cyclizations

Synthesis of tetrahydroimidazo[1,2-a]pyridines and tetrahydropyrido[1,2-a] pyrimidines by a one-pot and three component reaction of α-oxoketenedithioacetals, diamines and DMAD in water has been described. Different routes for accessing the desired compoun

SYNTHESIS OF BENZOYL SUBSTITUTED HETEROCYCLIC KETENE AMINALS BY CONDENSATION OF BENZOYL KETENE MERCAPTALS WITH DIAMINES

2-(Benzoylmethylene)imidazolidines 2 and 5, -hexahydropyrimidines 3 and 6, or -hexahydro-1H-1,3-diazepines 4 were synthesized by the reaction of benzoyl substituted ketene mercaptals 1 with diamines.