1073193-22-2

Basic information

• Product Name: ((C₅(CH₃)5)TiCl(C(Si(CH₃)3)C(C₆H₅)CH₂C₅(CH₃)4))
• CAS NO: 1073193-22-2
• Molecular Weight: 527.101
• Mol File: 1073193-22-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ((C₅(CH₃)5)TiCl(C(Si(CH₃)3)C(C₆H₅)CH₂C₅(CH₃)4))(CAS DataBase Reference)
• NIST Chemistry Reference: ((C₅(CH₃)5)TiCl(C(Si(CH₃)3)C(C₆H₅)CH₂C₅(CH₃)4))(1073193-22-2)
• EPA Substance Registry System: ((C₅(CH₃)5)TiCl(C(Si(CH₃)3)C(C₆H₅)CH₂C₅(CH₃)4))(1073193-22-2)

Safety Data

• Hazardous Substances Data: 1073193-22-2(Hazardous Substances Data)

Upstream product

• 1073193-06-2 ((C₅(CH₃)5)Ti(C(Si(CH₃)3)C(C₆H₅)CH₂C₅(CH₃)4)) 
• 7758-95-4 lead(II) chloride 

Relevant articles and documents

Sunlight photolysis of cyclopentadienyl–tethered titanium(iv) permethyltitanocene chlorides

Solutions of permethylcyclopentadienyl-tethered titanium(IV) chlorides incorporating one double bond in their tethers were exposed in glass vessels to sunlight, which triggered their photolytical reactions providing mixtures of products. Although the formation of several different products was apparent from 1H NMR spectra, only a single product could be identified in the crude reaction mixtures. This product was dicyclopentadiene [C10Me10], which arose from the recombination of the generally photodissociated C5Me5 radical. Amongst products that contained titanium, three complexes (3a, 3b and 4a) could be isolated after employing fractional crystallization and these complexes were characterized. The mechanism of 3a formation involves photodissociation of one η5-C5Me5 ligand from the parent complex, complemented by chlorine abstraction from another reactant molecule. Complexes 3b and 4a become formed via tether rearrangement, which starts with dissociating the tether Ti–C bond and is followed by rotating the tether, reattaching it subsequently through its available radical terminus.