1073277-19-6

Basic information

• Product Name: tert-butyl (1-(p-tolyl)allyl) carbonate
• Synonyms: tert-butyl (1-(p-tolyl)allyl) carbonate
• CAS NO: 1073277-19-6
• Molecular Weight: 248.322
• Mol File: 1073277-19-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: tert-butyl (1-(p-tolyl)allyl) carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl (1-(p-tolyl)allyl) carbonate(1073277-19-6)
• EPA Substance Registry System: tert-butyl (1-(p-tolyl)allyl) carbonate(1073277-19-6)

Safety Data

• Hazardous Substances Data: 1073277-19-6(Hazardous Substances Data)

Upstream product

• 104-87-0 4-methyl-benzaldehyde 
• 24424-99-5 di-tert-butyl dicarbonate 
• 58824-48-9 1-(4-methylphenyl)-2-propen-1-ol 
• 1826-67-1 vinyl magnesium bromide 

Downstream Products

• 363-72-4 Pentafluorobenzene 

Relevant articles and documents

Palladium-catalyzed salt-free double decarboxylative aryl allylation

This report describes a palladium-catalyzed decarboxylative aryl allylation between unactivated benzoic acids and allylic carbonates. This transformation successfully couples a variety of carbonates and benzoic acids in good yield (up to 94%) using 1 mol% palladium. This salt free allyl-arylation proceeds without added base, copper, or silver. The only stoichiometric byproducts are carbon dioxide and tert-butanol.

Highly Enantioselective Iridium-Catalyzed Coupling Reaction of Vinyl Azides and Racemic Allylic Carbonates

The iridium-catalyzed enantioselective coupling reaction of vinyl azides and allylic electrophiles is presented and provides access to β-chiral carbonyl derivatives. Vinyl azides are used as acetamide enolate or acetonitrile carbanion surrogates, leading to γ,δ-unsaturated β-substituted amides as well as nitriles with excellent enantiomeric excess. These products are readily transformed into chiral N-containing building blocks and pharmaceuticals. A mechanism is proposed to rationalize the chemoselectivity of this coupling reaction.