107557-54-0

Basic information

• Product Name: pentacarbonyl(triphenylstannyl triphenylstannanedithiocarboxylate)tungsten
• Synonyms: pentacarbonyl(triphenylstannyl triphenylstannanedithiocarboxylate)tungsten
• CAS NO: 107557-54-0
• Molecular Weight: 1100.1
• Mol File: 107557-54-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: pentacarbonyl(triphenylstannyl triphenylstannanedithiocarboxylate)tungsten(CAS DataBase Reference)
• NIST Chemistry Reference: pentacarbonyl(triphenylstannyl triphenylstannanedithiocarboxylate)tungsten(107557-54-0)
• EPA Substance Registry System: pentacarbonyl(triphenylstannyl triphenylstannanedithiocarboxylate)tungsten(107557-54-0)

Safety Data

• Hazardous Substances Data: 107557-54-0(Hazardous Substances Data)

Upstream product

• 14040-11-0 tungsten hexacarbonyl 
• 107557-47-1 triphenylstannyl triphenylstannanedithiocarboxylate 

Downstream Products

• 77-80-5 bis(triphenyltin) sulfide 

Relevant articles and documents

Nucleophilic Addition of Triorganotin Anions to Carbon Disulfide, IX. - Synthesis and Complexation of Novel Triphenylstannane Dithioesters

The known alkyl esters Ph3SnC(S)SR (1: R = Me, 2: R = CH2Ph) and the novel stannyl(methyl) esters (3: R = SnPh3, 4: R = CH2SnPh3) were obtained by the reaction of the dioxane adduct Ph3SnCS2Li*2C4H8O2 with appropriate organo(element) halides.As the first derivative of a homologous stannylalkanedithiocarboxylic acid, the 3-(triphenylstannyl)propane dithioester Ph3SnC(S)SMe (5) was synthesized by Grignard reaction of (3-chloropropyl)triphenylstannane with activated magnesium (addition of anthracene, ultrasound).The new η1-coordinated pentacarbonylchromium and -tungsten complexes LM(CO)5 (1a: L = 1, M = Cr; 2a: L = 2, M = Cr; 2b: L = 2, M = W; 3b: L = 3, M = W; 5b: L = 5, M = W) were prepared by modification of previously reported methods.