107816-54-6

Basic information

• Product Name: 4-[N-(4-methoxyphenyl)amino]benzaldehyde
• Synonyms: 4-[N-(4-methoxyphenyl)amino]benzaldehyde
• CAS NO: 107816-54-6
• Molecular Weight: 227.263
• Mol File: 107816-54-6.mol
• Article Data: 6

Chemical Properties

• Melting Point: 113 °C(Solv: hexane (110-54-3); chloroform (67-66-3))
• Boiling Point: 396.6±27.0 °C(Predicted)
• Density: 1.188±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 4-[N-(4-methoxyphenyl)amino]benzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 4-[N-(4-methoxyphenyl)amino]benzaldehyde(107816-54-6)
• EPA Substance Registry System: 4-[N-(4-methoxyphenyl)amino]benzaldehyde(107816-54-6)

Safety Data

• Hazardous Substances Data: 107816-54-6(Hazardous Substances Data)

Upstream product

• 104-92-7 1-bromo-4-methoxy-benzene 
• 122-85-0 para-acetamidobenzaldehyde 
• 107816-65-9 4-methoxy-4'-<2-(5,5-dimethyl-1,3-dioxanyl)>diphenylamine 
• 104-94-9 4-methoxy-aniline 
• 1122-91-4 4-bromo-benzaldehyde 
• 5720-07-0 4-methoxyphenylboronic acid 
• 555-16-8 4-nitrobenzaldehdye 
• 100-17-4 para-methoxynitrobenzene 
• 15164-44-0 p-(iodophenyl)carboxaldehyde 
• 104-88-1 4-chlorobenzaldehyde 
• 123-08-0 4-hydroxy-benzaldehyde 
• 107816-45-5 N-(4-methoxyphenyl)-4-<2-(5,5-dimethyl-1,3-dioxanyl)>acetanilide 
• 107816-41-1 5,5-dimethyl-2-(4-acetamidophenyl)-1,3-dioxan 
• 105114-53-2 1-bromo-4-(5,5-dimethyl-1,3-dioxan-2-yl)benzene 

Downstream Products

• 876732-73-9 N-(3-bromo-4-vinylphenyl)-N-(4-methoxypheny)-N-(4-vinylphenyl)amine 
• 908014-88-0 N-(4-{5-[N,N-bis(4-methoxyphenyl)amino]-2-methylstyryl}-3-methylphenyl)-N-(4-{5-[N,N-bis(4-methoxyphenyl)amino]-2-methylstyryl}phenyl)-4-methoxyaniline 
• 876732-76-2 N-(4-methoxyphenyl)-N-(3-methyl-4-vinylphenyl)-N-(4-vinylphenyl)amine 
• 876732-75-1 4-[N-(3-bromo-4-formylphenyl)-N-(4-methoxyphenyl)amino]benzaldehyde 
• 908014-90-4 4-[N-(4-formylphenyl)-N-(4-methoxyphenyl)amino]-2-methylbenzaldehyde 
• 18992-85-3 3-methoxycarbazole 
• 107816-72-8 6-methoxy-9H-carbazole-3-carbaldehyde 

Relevant articles and documents

Visible-Light- And PPh3-Mediated Direct C-N Coupling of Nitroarenes and Boronic Acids at Ambient Temperature

We present here a metal-free, visible-light- and triphenylphosphine-mediated intermolecular, reductive amination between nitroarenes and boronic acids at ambient temperature without any photocatalyst. Mechanistically, a slow reduction of nitroarenes to a nitroso and, finally, a nitrene intermediate occurs that leads to the amination product with concomitant 1,2-aryl/-alkyl migration from a boronate complex. A wide range of nitroarenes underwent C-N coupling with aryl-/alkylboronic acids providing high yields.

A group of diphosphine-thiosemicarbazone complexes of palladium: Efficient precursors for catalytic C–C and C–N coupling reactions

Reaction of 4-R-benzaldehyde thiosemicarbazone (denoted in general as HL-R; where H stands for the dissociable acidic proton and R (R = OCH3, CH3, H, Cl and NO2) for the substituent) with [Pd(dppe)(EtOH)2]2+, generated in situ via interaction of [Pd(dppe)Cl2] (dppe = 1,2-bis(diphenylphosphino)ethane) with AgNO3 in hot ethanol, in the presence of triethylamine affords a group of orange complexes of the type [Pd(dppe)(L-R)]NO3. Structures of [Pd(dppe)Cl2] and [Pd(dppe)(L-OCH3)]NO3 have been determined by X-ray crystallography. In the [Pd(dppe)(L-R)]NO3 complexes, the thiosemicarbazone ligands are coordinated to the metal center as monoanionic bidentate N,S-donors forming five-membered chelate rings. The [Pd(dppe)(L-R)]NO3 complexes show intense absorptions in the visible and ultraviolet regions, which have been analyzed by TDDFT calculations. All the [Pd(dppe)(L-R)]NO3 complexes are found to efficiently catalyze Suzuki-type C–C and Buchwald-type C–N coupling reactions.

Room-temperature high-spin organic single molecule: Nanometer-sized and hyperbranched poly[1,2,(4)-phenylenevinyleneanisylaminium]

Poly[1,2,(4)-phenylenevinyleneanisylaminium] 1 was synthesized by one-pot palladium-catalyzed polycondensation of N-(3-bromo-4-vinylphenyl)-N-(4- methoxyphenyl)-N-(4-vinylphenyl)amine 3 and subsequent oxidation with the thianthrene cation radical tetraflu