108215-26-5

Basic information

• Product Name: [μ-(1,4-diazabicyclo[2.2.2]octane)(phthalocyaninato)cobalt(II)*1.1 dichlorobenzene](n)
• Synonyms: [μ-(1,4-diazabicyclo[2.2.2]octane)(phthalocyaninato)cobalt(II)*1.1 dichlorobenzene](n)
• CAS NO: 108215-26-5
• Molecular Weight: 845.405
• Mol File: 108215-26-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [μ-(1,4-diazabicyclo[2.2.2]octane)(phthalocyaninato)cobalt(II)*1.1 dichlorobenzene](n)(CAS DataBase Reference)
• NIST Chemistry Reference: [μ-(1,4-diazabicyclo[2.2.2]octane)(phthalocyaninato)cobalt(II)*1.1 dichlorobenzene](n)(108215-26-5)
• EPA Substance Registry System: [μ-(1,4-diazabicyclo[2.2.2]octane)(phthalocyaninato)cobalt(II)*1.1 dichlorobenzene](n)(108215-26-5)

Safety Data

• Hazardous Substances Data: 108215-26-5(Hazardous Substances Data)

Upstream product

• 280-57-9 1,4-diaza-bicyclo[2.2.2]octane 
• 3317-67-7 cobalt(II) phthalocyanine 
• 108215-24-3 bis(1,4-diazabicyclo[2.2.2]octane)(phthalocyaninato)cobalt(II) 

Downstream Products

• 3317-67-7 cobalt(II) phthalocyanine 

Relevant articles and documents

Synthesis and Properties of (Phtalocyaninato)cobalt(II) Adducts with Nitrogen Bases

(α-) and (β-phtalocyaninato)cobalt(II) (PcCo) are treated with ligands L = pyrazine (pyz), 4-methylpyrazine (4-mepyz), pyridine (py), pyridine-d5 (py-d5), 4,4'-bipyridine (bpy), and n-butylamine (bu).The PcCo adducts PcCoL obtained (L = pyz, mepyz, me2pyz, Clpyz, py, py-d5, bu); PcCo-L-CoPc (L = bpy), n (L = pyz); PcCoL2 (L = pyz, py py-d5, pip, bpy), are characterized by ESR spectroscopy, thermal and magnetic measurements.Pentacoordinated complexes PcCoL are formed preferentially.Hexacoordinated complexes PcCoL2 with L = py, 4-mepy, bpy, pyz, piperidine (pip) are only formed at a high ligand concentration.While the polymer n was isolated as a stable compound, attempts to obtain n were unsuccessful.With 1,4-diazabicyclooctane (dabco), a strong ?-donor ligand, n is easily formed.In addition, the reaction of PcCo with 1,6-naphthyridine (naph), benzyl isocyanide (bzNC), and 1,4-diisocyanobenzene (dib) was also investigated.