108229-25-0

Basic information

• Product Name: (((3-methylbut-3-en-2-yl)oxy)methyl)benzene
• Synonyms: (((3-methylbut-3-en-2-yl)oxy)methyl)benzene
• CAS NO: 108229-25-0
• Molecular Weight: 176.258
• Mol File: 108229-25-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (((3-methylbut-3-en-2-yl)oxy)methyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (((3-methylbut-3-en-2-yl)oxy)methyl)benzene(108229-25-0)
• EPA Substance Registry System: (((3-methylbut-3-en-2-yl)oxy)methyl)benzene(108229-25-0)

Safety Data

• Hazardous Substances Data: 108229-25-0(Hazardous Substances Data)

Upstream product

• 54783-72-1 ethyl (S)-2-(benzyloxy)propionate 
• 16812-43-4 bis(trimethylstannyl)methane 
• 50-00-0 formaldehyd 
• 100-51-6 benzyl alcohol 
• 78-79-5 isoprene 
• 100-39-0 benzyl bromide 
• 10473-14-0 3-methyl-3-buten-2-ol 
• 113133-46-3 3-(phenylmethoxy)butan-2-one 
• 31729-70-1 bis(iodozinc)methane 
• 2040-44-0 ethyl 2-benzyloxypropionate 

Downstream Products

• 958264-94-3 C₂₀H₃₄OSi 

Relevant articles and documents

α-oxygen-atom induced methylenation of ketones by CH2(ZnI)2

Ketones bearing a hetero-atom at α-position were methylenated selectively by CH2(ZnI)2 to give allylic alcohols; a nucleophilic attack of the zinc species was accelerated with a coordination of a hetero-atom at α-position.

Metal-catalyzed silylene insertions of allylic ethers: Stereoselective formation of chiral allylic silanes

Silylene insertion into allylic ethers occurs suprafacially to provide enantioenriched allylic silanes and disilanes. Silylene insertion to a variety of protected allylic alcohols utilizing silver- and copper-mediated conditions proved to be a general method for allylic silane formation. Allylic disilanes reacted similarly to allylic silanes, undergoing both annulation and allylation reactions. Copyright

THE REACTION OF α-STANNYLMETHYLLITHIUM WITH ESTERS

Ketonic compounds were prepared from esters using α-stannylmethyllithium as the reagent.