1083094-24-9Relevant articles and documents
Stereoselective synthesis of tri- and tetrasubstituted alkenes by iron-catalyzed carbometalation ring-opening reactions of cyclopropenes
Wang, Yi,Fordyce, Euan A. F.,Chen, Fung Yan,Lam, Hon Wai
supporting information; experimental part, p. 7350 - 7353 (2009/04/10)
(Chemical Equation Presented) Open sesame: An iron-catalyzed cyclopropene carbometalation ring-opening sequence using trialkylaluminum reagents is described. The reactions proceed with high levels of regio- and stereo-control to provide a range of multisubstituted alkenes, including trisubstituted vinylsilanes, trisubstituted vinylstannanes, and all-carbon tetrasubstituted alkenes.