108534-55-0Relevant articles and documents
Phase-Transfer Catalyzed O-Silyl Ether Deprotection Mediated by a Cyclopropenium Cation
Mir, Roya,Dudding, Travis
, p. 709 - 714 (2017/04/26)
The use of a cyclopropenium cation as a phase-transfer catalyst for O-silyl ether deprotection is reported. Mechanistic insight into this deprotection methodology derived by linear free-energy relationships (LFER), quantum theory of atoms in molecules (QTAIM), and density functional theory (DFT) calculations are also provided.
Mixed Methyl Silyl Ketals of Quinones: Their Preparation via Anodic Oxidation and Their Chemistry
Stern, Alan,Swenton, John S.
, p. 2763 - 2768 (2007/10/02)
Anodic oxidation of tert-butyldimethylsilyl and tert-butyldiphenylsilyl derivatives of p-methoxyphenols affords quinone bisketals containing the uncommon alkyl silyl ketal unit.Acid hydrolysis of these quinone bisketals affords monoketals derived from hyd