108543-16-4Relevant articles and documents
Methyl 9-(2-(2,5-Dihydro-5-pentylfuryl))-nonanoate in the Copper-catalyzed Decomposition Products of Methyl Linoleate Hydroperoxide and Some Other Products
Tokita, Masako,Morita, Makio
, p. 309 - 314 (2007/10/02)
The hydroperoxide of methyl linoleate containing 95 percent 13-hydroperoxide and 5 percent 9-hydroperoxide was decomposed in benzene with 10-4 M cupric naphthenate at 7580 deg C under degassed conditions.The decomposition products were fractionated by Sephadex LH-20 column chromatography with chloroform-hexane (2 : 1, V/V) and the fractions were purified by HPLC.In addition to the known products, three compounds were identified as methyl 9-(2-(2,5-dihydro-5-pentylfuryl))-nonanoate, Methyl 8-(2-furyl)-octanoate, and methyl 9(13)-hydroperoxy-12,13-(9,10)-epoxy-10(12)-octadecenoate as miner decomposition products by MS and IR spectrophotometry.