108661-11-6

Basic information

• Product Name: pseudoneolongifolyl-p-bromobenzoate
• CAS NO: 108661-11-6
• Molecular Weight: 403.359
• Mol File: 108661-11-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: pseudoneolongifolyl-p-bromobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: pseudoneolongifolyl-p-bromobenzoate(108661-11-6)
• EPA Substance Registry System: pseudoneolongifolyl-p-bromobenzoate(108661-11-6)

Safety Data

• Hazardous Substances Data: 108661-11-6(Hazardous Substances Data)

Upstream product

• 91482-03-0 8,11-dibromolongibornane 
• 108643-00-1 11-acetoxylongicyclene 
• 108643-01-2 4-hydroxy-pseudoneolongifolene 
• 586-75-4 4-chlorobenzoyl chloride 

Relevant articles and documents

Silver Ion-Assisted Solvolysis of 8,11-Dibromolongibornane: Generation of Novel Skeletally Rearranged Olefinic Carbinols

The disecondary bromide, 8,11-dibromolongibornane (3) on exposure to silver perchlorate in aqueous acetone gives predominantly a mixture of three olefinic carbinols, of which a unique ring-expanded alcohol (7) constitutes 65percent; the assigned structure has been confirmed by an X-ray anaylsis of its p-bromobenzoate.Of the other two minor alcohols (separable only in the form of their ketones), one has been characterized as 10-ketolongifolene (15); the other keto-olefin which is highly hindered and resistant to Wolff-Kishner reduction has been assigned one of two possible structures 12/13 based on spectral data.The minor hydrocarbon fraction (6percent) has been shown to consist of two compounds of which only one has beencharacterized as dehydrolongifolene (22).