108893-72-7

Basic information

• Product Name: C₁₃H₁₉⁽²⁾HO
• CAS NO: 108893-72-7
• Molecular Weight: 193.293
• Mol File: 108893-72-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₃H₁₉⁽²⁾HO(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₁₉⁽²⁾HO(108893-72-7)
• EPA Substance Registry System: C₁₃H₁₉⁽²⁾HO(108893-72-7)

Safety Data

• Hazardous Substances Data: 108893-72-7(Hazardous Substances Data)

Upstream product

• 61899-98-7 2,6,6-trimethylcyclohex-2-en-1-ylidene ketene 
• 108893-70-5 C₁₃H₁₉⁽²⁾HO 

Relevant articles and documents

GRIGNARD AND HYDRIDE ADDITION TO A KETENE INTERMEDIATE: A NOVEL ACCESS TO α-DAMASCONE AND α-CYCLOCITRAL

α-Damascone (1), a rose fragrance chemical, was synthesized by an allylmagnesium chloride addition to ketene 7 as key step.When the same ketene 7 was reduced by two different aluminium hydride reagents, α-cyclocitral was obtained.The presumed intermediates, enolates II and III, were first trapped as silyl enol ethers and then hydrolyzed with D2O to give the expected α-monodeuterated carbonyl compounds.Mixed aluminium hydride reduction of ketenes is recommended as a facile entry into the chemistry of aldehyde enolates.