1089183-36-7

Basic information

• Product Name: (+)-(5S)-3-methyl-5-propylcyclohex-2-en-1-one
• Synonyms: (+)-(5S)-3-methyl-5-propylcyclohex-2-en-1-one
• CAS NO: 1089183-36-7
• Molecular Weight: 152.236
• Mol File: 1089183-36-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (+)-(5S)-3-methyl-5-propylcyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(5S)-3-methyl-5-propylcyclohex-2-en-1-one(1089183-36-7)
• EPA Substance Registry System: (+)-(5S)-3-methyl-5-propylcyclohex-2-en-1-one(1089183-36-7)

Safety Data

• Hazardous Substances Data: 1089183-36-7(Hazardous Substances Data)

Upstream product

• 1089183-45-8 C₁₀H₁₈O₂ 
• 1266679-05-3 (4S,5R)-3-methyl-4-(phenylsulfonyl)-5-propylcyclohex-2-enone 
• 1266679-09-7 C₁₂H₂₀S₂ 
• 5609-09-6 3-hepten-2-one 

Relevant articles and documents

Catalytic asymmetric michael reactions of α,β-unsaturated ketones with sulfonyl-containing nucleophiles: Chiral synthesis of (R)-muscone and (S)-celery ketone

An amine worth its salt: A highly enantioselective Michael addition reaction of α,β-unsaturated ketones with the sulfonyl-containing nucleophiles bis(phenylsulfonyl)methane and 1-(phenylsulfonyl)propan-2-one, catalyzed by a chiral primary amine salt, has been developed and gives excellent enantioselectivities (see scheme). The methodology has successfully demonstrated its synthetic utility in the chiral synthesis of (R)-muscone and (S)-celery ketone.

Primary-amine-catalyzed enantioselective intramolecular aldolizations

Aldol cyclodehydration of 4-substituted-2,6-heptanediones leads to enantiomerically enriched 5-substituted-3-methyl-2-cyclohexene-1-ones, which serve as perfume ingredients and valuable synthetic building blocks.Primary amines derived from cinchona alkalo