108961-85-9

Basic information

• Product Name: Phenyl-thiophosphonsaeure-O-10-(9-hydroxyphenanthryl)-O'-methyl-diester
• CAS NO: 108961-85-9
• Molecular Weight: 380.404
• Mol File: 108961-85-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phenyl-thiophosphonsaeure-O-10-(9-hydroxyphenanthryl)-O'-methyl-diester(CAS DataBase Reference)
• NIST Chemistry Reference: Phenyl-thiophosphonsaeure-O-10-(9-hydroxyphenanthryl)-O'-methyl-diester(108961-85-9)
• EPA Substance Registry System: Phenyl-thiophosphonsaeure-O-10-(9-hydroxyphenanthryl)-O'-methyl-diester(108961-85-9)

Safety Data

• Hazardous Substances Data: 108961-85-9(Hazardous Substances Data)

Upstream product

• 3497-00-5 phenylthiophosphonic acid dichloride 
• 84-11-7 9,10-phenanthrenequinone 
• 604-84-2 phenanthrene-9,10-diol 
• 67-56-1 methanol 
• 108961-80-4 2-Phenyl-phenanthro<9,10-d>-1,3,2-dioxaphosphol-2-sulfid 

Downstream Products

• 108961-80-4 2-Phenyl-phenanthro<9,10-d>-1,3,2-dioxaphosphol-2-sulfid 

Relevant articles and documents

Phosphorus Compounds with Unusual Coordination, 13. Trapping Reactions of Phenyl Thioxophosphane by Cycloaddition with o-Quinones

Phenyl thioxophosphane (1) - generated by thermal cycloreversion from 7 along with the dihydropyridazine 8 - is trapped by cycloaddition with the o-quinones 9a-f by formation of the dioxaphospholsulfides 10a-f.Solvolysis of 10a-c, e and f with methanol yields the phenol derivatives 12a-e (in the case of 10b the isomer 12b' is formed, too).This reaction is reversible (12a-c-->10a-c) and accompanied by formation of the isomers 13a-c.The phenanthrene quinone methanide 14 is also suitable for the trapping reaction of 1 (-->15-->17). - Keywords: Phenyl Thioxophosphane, o-Quinones, -Cycloaddition, 1,3,2-Benzodioxaphosphol-2-sulfides