109005-38-1

Basic information

• Product Name: Benzene, 4-methoxy-2-[[(4-methylphenyl)sulfonyl]methyl]-1-nitro-
• CAS NO: 109005-38-1
• Molecular Formula: C15H15NO5S
• Molecular Weight: 321.354
• Mol File: 109005-38-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 4-methoxy-2-[[(4-methylphenyl)sulfonyl]methyl]-1-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 4-methoxy-2-[[(4-methylphenyl)sulfonyl]methyl]-1-nitro-(109005-38-1)
• EPA Substance Registry System: Benzene, 4-methoxy-2-[[(4-methylphenyl)sulfonyl]methyl]-1-nitro-(109005-38-1)

Safety Data

• Hazardous Substances Data: 109005-38-1(Hazardous Substances Data)

Upstream product

• 100-17-4 para-methoxynitrobenzene 
• 7569-26-8 chloromethyl p-tolylsulfone 
• 446-38-8 2-fluoro-4-methoxy-1-nitro-benzene 

Downstream Products

• 142452-37-7 (5-methoxy-2-nitrophenyl)-cyclohexylidenemethane 
• 109049-92-5 7-Methoxy-9-(toluene-4-sulfonyl)-2,3-dihydro-1H-pyrrolo[1,2-a]indole 
• 109005-39-2 4-methoxy-2-<<(4-methylphenyl)sulfonyl>methyl>benzenamine 
• 20357-24-8 5-methoxy-2-nitro-benzaldehyde 
• 142452-32-2 1-(5-methoxy-2-nitrophenyl)-2-methylpropene 
• 142452-38-8 2-(5-methoxy-2-nitrobenzyl)-2-nitropropane 

Relevant articles and documents

Direct observation of the intermediate in vicarious nucleophilic substitutions of hydrogen

Mononitrobenzene derivatives and 1-chloro-1-arylsulfonyl-methyl anions react with formation of stable σH adducts (see scheme; Ts = tosyl) which are observed by UV/Vis and NMR spectroscopy. The generally accepted energy profiles for vicarious nu

SYNTHESIS OF DIHYDRO-1H-PYRROLO- AND TETRAHYDROPYRIDOINDOLES VIA A MODIFIED MADELUNG REACTION

1-(2-Methylphenyl)lactams 9, having different electron -withdrawing groups at the benzylicposition, cyclize under the influence of sodium hydride or potassium tert-butoxyde.Depending on the ring size of the lactam moiety dihydropyrrolo- (10), tetrahydropyridoindole (11), or dihydro-1H-1-benzazepine (12) derivatives are formed.Pyrroloindole 10c has been converted into the corresponding quione 15b.Starting from naphthaleneacetonitrile 20, prepared in 5 steps from 2,3-dichloronaphthoquinone, the 5,10-dioxo-1H-pyrollobenzindole 22 is obtained upon treatment with base and subsequent oxidation of the protected hydroquinone function with ceric ammonium nitrate.