109179-31-9Relevant articles and documents
An Industrial Perspective on Counter Anions in Gold Catalysis: On Alternative Counter Anions
Schie?l, Jasmin,Schulmeister, Jürgen,Doppiu, Angelino,W?rner, Eileen,Rudolph, Matthias,Karch, Ralf,Hashmi, A. Stephen K.
, p. 3949 - 3959 (2018)
A comparison of versatile counter anions was investigated by means of a variety of well-known test reactions representing the key reactivity patterns of homogeneous gold catalysis, the catalytic activity was monitored by GC and 1H NMR. As previ
Selective Oxidation of 2-Bromo-m-xylene to 2-Bromo-3-methylbenzoic Acid or 2-Bromoisophthalic Acid
Miyano, Sotaro,Fukushima, Hiroshi,Inagawa, Hideho,Hashimoto, Harukichi
, p. 3285 - 3286 (1986)
Aqueous sodium dichromate oxidation of 2-bromo-m-xylene (1) under a carbon dioxide pressure gave 2-bromoisophthalic acid (58percent), while NBS-bromination of 1 followed by Sommelet oxidation to aldehyde and then potassium permanganate oxidation enabled t
LIGHT INDUCED CATALYTIC C-H OXYGENATION OF ALKANES
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Paragraph 00219, (2021/04/02)
A method of oxygenating a benzylic C-H bond is provided. The method comprises light induced activation of an initiator and subsequent reaction with oxygen, resulting in the formation of free radicals. Subsequently, free radicals catalyze the reaction of the benzylic C-H bond with oxygen, thereby forming an oxygenated compound.
An Industrial Perspective on Counter Anions in Gold Catalysis: Underestimated with Respect to “Ligand Effects”
Schie?l, Jasmin,Schulmeister, Jürgen,Doppiu, Angelino,W?rner, Eileen,Rudolph, Matthias,Karch, Ralf,Hashmi, A. Stephen K.
supporting information, p. 2493 - 2502 (2018/04/25)
The conversion of a variety of well-known test reactions, representing the key reactivity patterns of gold catalysis, were analyzed by GC and 1H NMR. The study is focused on establishing of a strategical approach for the consideration of ligand