1092559-79-9Relevant articles and documents
A new type of oxidation-reduction condensation by the combined use of phenyl diphenylphosphinite and oxidant
Mukaiyama, Teruaki,Kuroda, Kiichi,Maruyama, Yuji
scheme or table, p. 63 - 82 (2010/04/23)
A new type of oxidation-reduction condensation of alcohols with sulfur, nitrogen, and oxygen nucleophiles by the combined use of phenyl diphenylphosphinite (PhOPPh2) and oxidants such as azides or diethyl azodicarboxylate (DEAD) are described. In these reactions, chiral secondary and tertiary alcohols are converted into the corresponding chiral sulfides, azides, esters and ethers under mild and neutral conditions with almost complete inversion of stereochemical configuration.
Stereospecific synthesis of sec- and tert-alkyl azides from alcohols and trimethylsilyl azide by a new type of oxidation-reduction condensation using phenyl diphenylphosphinite and trimethylsilylmethyl azide
Mukaiyama, Teruaki,Kuroda, Kiichi,Maruyama, Yuji,Hayashi, Yujiro
scheme or table, p. 1072 - 1073 (2009/12/02)
A novel method for the preparation of alkyl azides from alcohols and trimethylsilyl azide by a new type of oxidation-reduction condensation using phenyl diphenylphosphinite and trimethylsilylmethyl azide is described. Chiral secondary and tertiary alcohols are converted into the corresponding chiral azides with almost complete inversion of configuration under mild and neutral conditions. Copyright
