1092728-57-8

Basic information

• Product Name: C₂₁H₃₂N₂O₃Si
• CAS NO: 1092728-57-8
• Molecular Weight: 388.582
• Mol File: 1092728-57-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₁H₃₂N₂O₃Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₁H₃₂N₂O₃Si(1092728-57-8)
• EPA Substance Registry System: C₂₁H₃₂N₂O₃Si(1092728-57-8)

Safety Data

• Hazardous Substances Data: 1092728-57-8(Hazardous Substances Data)

Upstream product

• 1092728-56-7 C₁₄H₁₇NO₃ 
• 56522-24-8 tert-butyldimethylsilyl cyanide 

Relevant articles and documents

Direct synthesis of protected enantiopure 5-cyano-3,4-dihydroxypyrrolidin- 2-ones from β-lactam aldehydes catalyzed by iodine

A single-step catalytic ring-expansion approach from 4-oxoazetidine-2- carbaldehydes to protected enantiopure 5-cyano-3,4-dihydroxypyrrolidin-2-ones has been achieved by the use of the commercially available and inexpensive reagent, molecular iodine, in the presence of tert-butyldimethyl cyanide. Interestingly, the catalyst directs the reaction toward the selective rearrangement reaction of the β-lactam nucleus rather than cyanohydrin formation. Georg Thieme Verlag Stuttgart.