109283-59-2

Basic information

• Product Name: Silane, trimethyl[(2-methylcyclohexyl)oxy]-
• CAS NO: 109283-59-2
• Molecular Formula: C10H22OSi
• Molecular Weight: 186.37
• Mol File: 109283-59-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[(2-methylcyclohexyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[(2-methylcyclohexyl)oxy]-(109283-59-2)
• EPA Substance Registry System: Silane, trimethyl[(2-methylcyclohexyl)oxy]-(109283-59-2)

Safety Data

• Hazardous Substances Data: 109283-59-2(Hazardous Substances Data)

Upstream product

• 583-59-5 2-Methylcyclohexanol 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 583-60-8 2-Methylcyclohexanone 
• 75-77-4 chloro-trimethyl-silane 
• 557-20-0 diethylzinc 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 75-24-1 trimethylaluminum 
• 286-20-4 cyclohexane-1,2-epoxide 

Downstream Products

• 74173-09-4 2-Methyl-2-trimethylsilyloxy-1-cyclohexanon 
• 583-60-8 2-Methylcyclohexanone 

Relevant articles and documents

A novel and highly efficient method for the silylation of alcohols with hexamethyldisilazane (HMDS) catalyzed by recyclable sulfonic acid-functionalized ordered nanoporous silica

Silylation of alcohols with hexamethyldisilazane (HMDS) in dichloromethane provides the corresponding silyl ethers in almost quantitative yields at room temperature using 1-3 mol % of sulfonic acid-functionalized silica. Additionally, the catalyst display

KF/clinoptilolite NPs: An efficient and heterogeneous catalyst for chemoselective silylation of alcohols and phenols

Potassium fluoride incorporated on clinoptilolite nanoparticles (KF/CP NPs) by ion exchanging is found to be an effective and inexpensive heterogeneous nanocatalyst for chemoselective silylation of alcohols and phenols with 1,1,1,3,3,3-hexamethyldisilazane (HMDS) at room temperature. Nano-powder of clinoptilolite (CP) was prepared using a planetary ball mill mechanically method and characterized by dynamic light scattering (DLS), X-ray powder diffraction (XRD) and scanning electron microscope (SEM) analyses. Almost all of products were obtained in high yields as well as short reaction times and the catalyst was also reused eight times without loss of its catalytic activity.

New method for the synthesis of 2-aza-1,3-butadienes

2-Aza-1,3-butadienes have been synthesized from carbonyl compounds and 1,1,1,3,3,3-hexamethyl-disilazane in the presence of cobalt-containing catalysts. The best yields (up to 95%) were achieved in the case of aldehydes branched in the α-position and 2-methylcyclohexanone. In the case of two α,β-unsaturated ketones, pyridine derivatives were found as the main products. Copyright Taylor & Francis Group, LLC.