1092961-95-9Relevant articles and documents
Synthesis of (+)-sucrose via β-d-psicofuranosylation
Uenishi, Jun'ichi,Ueda, Atsushi
experimental part, p. 2210 - 2217 (2009/04/04)
Despite the difficulty of direct β-furanosylation with d-fructose, the synthesis of β-d-fructofuranosyl α-d-glucopyranoside, (+)-sucrose 1, has been achieved stepwise, via β-selective d-psicofuranosylation followed by stereo inversion of a hydroxy group at the C-3 position on the furanose ring. d-Psicofuranosyl donor 10 was prepared in eight steps from d-ribose monoacetonide 3 in excellent yield.