109572-55-6

Basic information

• Product Name: (E)-2-(Hydroxy-phenyl-methyl)-1-iodo-oct-1-en-3-one
• Synonyms: (E)-2-(Hydroxy-phenyl-methyl)-1-iodo-oct-1-en-3-one
• CAS NO: 109572-55-6
• Molecular Weight: 358.219
• Mol File: 109572-55-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-2-(Hydroxy-phenyl-methyl)-1-iodo-oct-1-en-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(Hydroxy-phenyl-methyl)-1-iodo-oct-1-en-3-one(109572-55-6)
• EPA Substance Registry System: (E)-2-(Hydroxy-phenyl-methyl)-1-iodo-oct-1-en-3-one(109572-55-6)

Safety Data

• Hazardous Substances Data: 109572-55-6(Hazardous Substances Data)

Upstream product

• 27593-19-7 oct-1-yn-3-one 
• 100-52-7 benzaldehyde 
• 1125-88-8 benzaldehyde dimethyl acetal 

Relevant articles and documents

ALDOL REACTION OF ALLENOLATES GENERATED VIA 1,4-ADDITION OF IODIDE ANION OR ITS EQUIVALENT TO α,β-ACETYLENIC KETONES

TMSI, Et2AlI, and (n-Bu)4NI/TiCl4 smoothly added to α,β-acetylenic ketones in a 1,4-fashion to yield allenolates 2, which reacted with aldehydes providing aldol adducts in good overall yield.A high Z-stereoselectivity was achieved by use of (n-Bu)4NI/TiCl4 at -78 deg C, while a high E-stereoselectivity occured at 0 deg C.