1095873-95-2

Basic information

• Product Name: ethyl (2Z,4E)-2-azido-5-(2-methoxyphenyl)penta-2,4-dienoate
• Synonyms: ethyl (2Z,4E)-2-azido-5-(2-methoxyphenyl)penta-2,4-dienoate
• CAS NO: 1095873-95-2
• Molecular Weight: 273.291
• Mol File: 1095873-95-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl (2Z,4E)-2-azido-5-(2-methoxyphenyl)penta-2,4-dienoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (2Z,4E)-2-azido-5-(2-methoxyphenyl)penta-2,4-dienoate(1095873-95-2)
• EPA Substance Registry System: ethyl (2Z,4E)-2-azido-5-(2-methoxyphenyl)penta-2,4-dienoate(1095873-95-2)

Safety Data

• Hazardous Substances Data: 1095873-95-2(Hazardous Substances Data)

Upstream product

• 637-81-0 ethyl-2-azidoacetate 
• 60125-24-8 (E)-3-(2-methoxyphenyl)propenal 
• 1504-74-1 2-methoxycinnamaldehyde 

Downstream Products

• 1095874-17-1 ethyl 5-(2-methoxyphenyl)-6-(4-nitrolbenzyl)picolinate 
• 1095874-15-9 ethyl 6-(4-methoxybenzyl)-5-(2-methoxyphenyl)picolinate 
• 1095874-11-5 ethyl 6-benzyl-5-(2-methoxyphenyl)picolinate 
• 1095874-13-7 ethyl 5-(2-methoxyphenyl)-6-(4-methylbenzyl)picolinate 

Relevant articles and documents

Cascade aza-Wittig/6π-Electrocyclization in the Synthesis of 1,6-Dihydropyridines

A metal-free protocol for the synthesis of substituted 1,6-dihydropyridines with quaternary stereogenic centers via a cascade aza-Wittig/6π-electrocyclization process has been developed. The high functional group compatibility and broad scope of this method were demonstrated by using a wide range of easily available vinyliminophosphoranes and ketones, with yields up to 97%. A modification of the obtained products allowed for an increase in complexity and chemical diversity. Finally, attempts for asymmetric synthesis of 1,6-dihydropyridines are demonstrated.