1097259-10-3

Basic information

• Product Name: methyl 3-(4-nitrophenyl)-2-methyl-3-oxopropanoate
• Synonyms: methyl 3-(4-nitrophenyl)-2-methyl-3-oxopropanoate
• CAS NO: 1097259-10-3
• Molecular Weight: 237.212
• Mol File: 1097259-10-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 3-(4-nitrophenyl)-2-methyl-3-oxopropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-(4-nitrophenyl)-2-methyl-3-oxopropanoate(1097259-10-3)
• EPA Substance Registry System: methyl 3-(4-nitrophenyl)-2-methyl-3-oxopropanoate(1097259-10-3)

Safety Data

• Hazardous Substances Data: 1097259-10-3(Hazardous Substances Data)

Upstream product

• 114106-93-3 methyl 2-[hydroxy(4-nitrophenyl)methyl]prop-2-enoate 
• 34757-14-7 methyl 2-diazopropanoate 
• 636-98-6 p-nitrobenzene iodide 
• 201230-82-2 carbon monoxide 
• 555-16-8 4-nitrobenzaldehdye 

Relevant articles and documents

Pentamethylcyclopentadienyl ruthenium: an efficient catalyst for the redox isomerization of functionalized allylic alcohols into carbonyl compounds

The catalytic activity of the ruthenium(II) complex [RuCp*(CH3CN)3][PF6] 1 in the transposition of allylic alcohols into carbonyl compounds, in acetonitrile, is reported. This catalyst has proven to be able to catalyze the transformation of poorly reactive and/or functionalized substrates under smooth conditions.

Palladium-catalyzed carbonylation/acyl migratory insertion sequence

Chemical Equation Presented On the move: A palladium-catalyzed reaction of aryl iodides, diazo compounds or N-tosylhyd razones, and carbon monoxide affords β-oxo esters or ketones/ enones (see scheme; DCE = l,2-dichloroethane). The products are delivered with high efficiency through the title sequence.