110022-38-3

Basic information

• Product Name: trans-{iron(II)Cl(MeNC)(Me₂PCH₂CH₂PMe₂)2}{BPh₄}
• CAS NO: 110022-38-3
• Molecular Weight: 751.867
• Mol File: 110022-38-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-{iron(II)Cl(MeNC)(Me₂PCH₂CH₂PMe₂)2}{BPh₄}(CAS DataBase Reference)
• NIST Chemistry Reference: trans-{iron(II)Cl(MeNC)(Me₂PCH₂CH₂PMe₂)2}{BPh₄}(110022-38-3)
• EPA Substance Registry System: trans-{iron(II)Cl(MeNC)(Me₂PCH₂CH₂PMe₂)2}{BPh₄}(110022-38-3)

Safety Data

• Hazardous Substances Data: 110022-38-3(Hazardous Substances Data)

Upstream product

• 110-54-3 hexane 
• 23936-60-9 1,2-bis(dimethylphosphanyl)ethane 
• 143-66-8 sodium tetraphenyl borate 
• 130172-25-7 {iron(II)Cl(dinitrogen)(Me₂PCH₂CH₂PMe₂)2}{BPh₄} 
• 593-75-9 methyl isocyanate 
• 110005-53-3 trans-acetonitrile-bis(1,2-bis(dimethylphosphino)ethane)chloroiron(II) chloride 

Relevant articles and documents

Synthesis and structure of singly bridged and doubly bridged [MoFe(3)S(4)] double cubanes with bidentate phosphine ligands.

The reactions of the (Et(4)N)(2)[(Cl(4)-cat)(MeCN)MoFe(3)S(4)Cl(3)] (I) cluster with Fe(pp)(2)Cl(2) (pp = depe (bis(1,2-diethylphosphino)ethane) or dmpe (bis(1,2-dimethylphosphino)ethane)) produced the [(Cl(4)-cat)MoFe(3)S(4)(pp)(2)Cl](2)(mu-pp) (pp = depe (III) or dmpe (V)) singly bridged double cubanes. The reactions of I with the same bidentate phosphine ligands in the presence of NaBPh(4) also produced III and the [(Cl(4)-cat)MoFe(3)S(4)(dmpe)(2)](2)(mu-S)(mu-dmpe) (VI) doubly bridged double cubane, respectively. The byproduct (BPh(4))[Fe(dmpe)(2)(MeCN)Cl] (VII) has been isolated from the reaction mixture and crystallographically characterized. The depe analogue of VI, [(Cl(4)-cat)MoFe(3)S(4)(depe)(2)](2)(mu-S)(mu-depe) (IV), has been successfully prepared from III in the presence of excess Li(2)S. Similar reactions with (Et(4)N)(2)[Fe(4)S(4)(SPh)(4)] (VIII) have resulted in the formation of the neutral Fe(4)S(4)(depe)(2)(SPh)(2) (IX) cluster. The chloride analogue of IX, Fe(4)S(4)(depe)(2)Cl(2) (XI), has been obtained by a reaction of IX with benzoyl chloride. The crystal and molecular structures of III, VI, VII, and XI have been determined by single-crystal X-ray crystallography. The electrochemical and spectroscopic properties, including the Mossbauer spectra of the new clusters, have been determined and analyzed.