110210-18-9

Basic information

• Product Name: Benzene, 1-[1-iodo-2-[(4-methylphenyl)sulfonyl]ethenyl]-3-nitro-, (Z)-
• CAS NO: 110210-18-9
• Molecular Formula: C15H12INO4S
• Molecular Weight: 429.235
• Mol File: 110210-18-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[1-iodo-2-[(4-methylphenyl)sulfonyl]ethenyl]-3-nitro-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[1-iodo-2-[(4-methylphenyl)sulfonyl]ethenyl]-3-nitro-, (Z)-(110210-18-9)
• EPA Substance Registry System: Benzene, 1-[1-iodo-2-[(4-methylphenyl)sulfonyl]ethenyl]-3-nitro-, (Z)-(110210-18-9)

Safety Data

• Hazardous Substances Data: 110210-18-9(Hazardous Substances Data)

Upstream product

• 3034-94-4 3-nitrophenylacetylene 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 1950-78-3 p-toluenesulfonyl iodide 

Downstream Products

• 1089311-11-4 C₁₅H₁₃NO₄S 

Relevant articles and documents

CAN mediated reaction of aryl sulfinates with alkenes and alkynes: Synthesis of vinyl sulfones, β-iodovinyl sulfones and acetylenic sulfones

Cerium(IV) ammonium nitrate (CAN) mediated reaction of aryl sulfinates and sodium iodide with alkenes afforded vinyl sulfones in very good yields. Alkynes underwent similar reaction to give β-iodovinyl sulfones, which on treatment with potassium carbonate

Addition of Arenesulphonyl Iodides to Substituted Phenylacetylenes

The products of the addition of toluene-p-sulphonyl iodide to substituted phenylacetylenes (and styrenes) are studied.The regiospecificity and stereoselectivity of trans addition to acetylenes is inferred from (1)H n.m.r. spectroscopy.The effect of substituents on the reactivity of substituted phenylacetylenes towards substituted beenzenesulphonyl radicals generated by photolysis of sulphonyl iodides is studied.Phenylacetylenes with electron-donating substituents react faster.Relative reactivities yield good Hammet-Brown correlations showing the electrophilic character of sulphonyl radicals towards phenylacetylenes.The selectivity of the addition (measured by ρ) of different sulphonyl radicals towards the same set of acetylenes ranges from -0.53 to -0.93 and shows a tendency to be smaller for benzenesulphonyl iodides carrying electron donating substituents.Results are discussed in terms of polar effects on the transition state and frontier molecular orbital theory.