110314-99-3

Basic information

• Product Name: 5(4H)-Oxazolone, 4-(4-methoxyphenyl)-2-(4-methylphenyl)-
• CAS NO: 110314-99-3
• Molecular Formula: C17H15NO3
• Molecular Weight: 281.311
• Mol File: 110314-99-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5(4H)-Oxazolone, 4-(4-methoxyphenyl)-2-(4-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 5(4H)-Oxazolone, 4-(4-methoxyphenyl)-2-(4-methylphenyl)-(110314-99-3)
• EPA Substance Registry System: 5(4H)-Oxazolone, 4-(4-methoxyphenyl)-2-(4-methylphenyl)-(110314-99-3)

Safety Data

• Hazardous Substances Data: 110314-99-3(Hazardous Substances Data)

Upstream product

• 110315-01-0 2-(4-methoxyphenyl)-N-(4-methylbenzoyl)glycine 
• 874-60-2 4-methyl-benzoyl chloride 
• 2540-53-6 2-(4-methoxyphenyl)glycine 

Downstream Products

• 110315-14-5 3-(4-methoxyphenyl)-1-(4-methylbenzoyloxy)-6-nitro-1H-pyrazolo<4,3-b>pyridine 
• 110315-10-1 4-(3,5-dinitro-2-pyridyl)-2-(4-methoxyphenyl)-2-(4-methylphenyl)-5(4H)-oxazolone 
• 110315-19-0 3-(4-methoxyphenyl)-6-nitro-1H-indazol-1-ol 
• 99-75-2 4-methyl-benzoic acid methyl ester 
• 110315-07-6 4-(2,4-dinitrophenyl)4-(4-methoxyphenyl)-2-(4-methylphenyl)-5(4H)-oxazolone 

Relevant articles and documents

5-Oxazolones, II 2,4-Diaryl-4-(2,4-dinitroaryl)-5(4H)-oxazolones: Synthesis and Acid-Catalyzed Transformation into 1-Hydroxy-1H-indazole Derivatives

2,4-Diaryl-4-(2,4-dinitroaryl)-5(4 H)-oxazolones 2 were prepared by arylation of the corresponding 5(4H)-oxazolones 1 under phase-transfer conditions with the corresponding 1-halo-2,4-dinitrobenzenes. 2,4-Diaryl-4-(3,5-dinitro-2-pyridyl)-5(4H)-oxazolones 5 were obtained similarly from the corresponding 1 and 2-chloro-3,5-dinitropyridine.On reaction with methanol and p-toluenesulfonic acid , oxazolones 2 rearranged to the corresponding 1-hydroxy-1H-indazole derivatives 8.Under the same conditions oxazolones 5 afforded a mixture of the correspondingly substituted 1H-pyrazolopyridines 7 and substituted imidazopyridines 12.In all cases the solvolysis reaction, yielding substituted glycine esters 9 and 11, was competitive with the rearrangement.Reaction path are discussed.