110320-03-1Relevant articles and documents
cine-Substitution in Halogenobenzenetricarbonylchromium Complexes
Rose-Munch, Francoise,Rose, Eric,Semra, Assia
, p. 1551 - 1552 (1986)
cine-Substitution of the chloro group of chlorobenzenetricarbonylchromium complexes by a carbon nucleophile has been observed.
Substitutions nucleophiles aromatiques SNAr cine et tele sur l'ortho, le meta et le para-chlorotoluenetricarbonylchrome
Rose-Munch, Francoise,Rose, Eric,Semra, Assia,Bois, Claudette
, p. 103 - 122 (2007/10/02)
The study of the regioselectivity of the addition of a nucleophile to chlorotoluenetricarbonylchromium complexes, under cine or tele SNAr conditions, indicated that stabilized carbanions added predominantly to the carbon eclipsed by a Cr-CO bond of the most stable conformer.The conformation of p-chlorotoluenetricarbonylchromium has been studied, in solution by 1H NMR and in the solid state by X-ray crystallography.