1103686-40-3

Basic information

• Product Name: (1R,6R)-5,5,10,10-tetraphenyl-3,8-bis(3-methoxyphenyl)-2,4,7,9-tetraoxa-3,8-diboro-bicyclo[4.4.0]decane
• CAS NO: 1103686-40-3
• Molecular Weight: 658.366
• Mol File: 1103686-40-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,6R)-5,5,10,10-tetraphenyl-3,8-bis(3-methoxyphenyl)-2,4,7,9-tetraoxa-3,8-diboro-bicyclo[4.4.0]decane(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,6R)-5,5,10,10-tetraphenyl-3,8-bis(3-methoxyphenyl)-2,4,7,9-tetraoxa-3,8-diboro-bicyclo[4.4.0]decane(1103686-40-3)
• EPA Substance Registry System: (1R,6R)-5,5,10,10-tetraphenyl-3,8-bis(3-methoxyphenyl)-2,4,7,9-tetraoxa-3,8-diboro-bicyclo[4.4.0]decane(1103686-40-3)

Safety Data

• Hazardous Substances Data: 1103686-40-3(Hazardous Substances Data)

Upstream product

• 10365-98-7 3-methoxyphenylboronic acid 
• 117780-08-2 (+)?(2R,3R)?1,1?4,4?tetraphenylbutane?1,2,3,4?tetraol 

Relevant articles and documents

Selective 1,3-cycloboronation of enantiopure 1,1,4,4-tetrasubstituted butanetetraols: versatile preparation, structural characterization, and properties of chiral cyclic boron-containing bifunctional Lewis acids

The selective cycloboronation of enantiopure 1,1,4,4-tetrasubstituted butanetetraols was investigated, and a general preparation of chiral cyclic boron-containing bifunctional Lewis acids was discovered. Compounds (2R,3R)- or (2S,3S)-1,1,4,4-tetrasubstituted butanetetraols were reacted with ArB(OH)2 at reflux in toluene, or THF, or under solvent-free condition to furnish tricoordinated, chiral bicyclo[4.4.0]diboronic esters in high yield via selective 1,3-cycloboronation. Structural characterization and properties of the novel chiral boron compounds are also reported.