1104028-99-0

Basic information

• Product Name: Methyl-4,4,4-trifluoro-3-phenylbut-2-enoate
• Synonyms: Methyl-4,4,4-trifluoro-3-phenylbut-2-enoate
• CAS NO: 1104028-99-0
• Molecular Weight: 230.186
• Mol File: 1104028-99-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Methyl-4,4,4-trifluoro-3-phenylbut-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl-4,4,4-trifluoro-3-phenylbut-2-enoate(1104028-99-0)
• EPA Substance Registry System: Methyl-4,4,4-trifluoro-3-phenylbut-2-enoate(1104028-99-0)

Safety Data

• Hazardous Substances Data: 1104028-99-0(Hazardous Substances Data)

Upstream product

• 434-45-7 2,2,2-Trifluoroacetophenone 
• 105245-42-9 tert-butyl(1-methoxyvinyl)dimethylsilane 
• 83961-54-0 methyl 4,4,4-trifluoro-3-oxo-2-(triphenylphosphoranylidene)butanoate 
• 591-51-5 phenyllithium 

Downstream Products

• 1104029-00-6 methyl 4,4,4-trifluoro-3-phenylbutanoate 

Relevant articles and documents

Mukaiyama aldol reactions catalyzed by a trimeric organo aluminum(III) alkoxide

Mukaiyama aldol reactions of enol ethers with a variety of aldehydes and ketones are efficiently catalyzed at 0-25 °C by the sterically bulky trimeric organo aluminum(III) alkoxide 1 synthesized via the reaction of 3 equiv of AlMe3 with tripodal tris(2-hydroxy-3-tert-butyl-5-methylphenyl) methane and the elimination of 3 equiv of methane. Comparisons of its catalytic properties with the less sterically hindered analogue 2, the more sterically hindered analogue 3, a monomeric aluminum near-analogue 4, and a dimeric alumatrane 5 revealed that 1 possesses superior activity.