1104516-08-6Relevant articles and documents
Rhenium- and manganese-catalyzed insertion of alkynes into a carbon-carbon single bond of cyclic and acyclic 1,3-dicarbonyl compounds
Kuninobu, Yoichiro,Kawata, Atsushi,Nishi, Mitsumi,Yudha S, Salprima,Chen, Jingjin,Takai, Kazuhiko
experimental part, p. 1424 - 1433 (2010/04/23)
Treatment of alkynes with cyclic and acyclic 1,3-dicarbonyl compounds in the presence of a catalytic amount of a rhenium or manganese complex gives ring-expanded and carbon-chain extension products, respectively. In these reactions, alkynes insert into a