110590-29-9Relevant articles and documents
Direct evidence for a ruthenium(IV) oxo complex-mediated oxidation of a hydroxamic acid in the presence of phosphine oxide donors
Flower,Lightfoot,Wan,Whiting
, p. 1812 - 1813 (2001)
Ruthenium(II) complexes can be used to oxidise N-Boc hydroxylamine in the presence of tert-butylhydroperoxide to the corresponding nitroso dienophile, which is trapped using cyclohexa-1,3-diene as the hetero-Diels-Alder adduct; direct evidence has been obtained for the intervention of a triphenylphosphine oxide-stabilised ruthenium(IV) oxo-complex as the catalytically active species.
The oxidative acylnitroso hetero-diels-alder reaction catalyzed by dirhodium caprolactamate
Tusun, Xiarepati,Lu, Chong-Dao
, p. 1801 - 1804 (2012)
An effective protocol is described for the generation and in situ Diels-Alder trapping of acylnitroso derivatives. In this procedure, the oxidation of hydroxamic acid is efficiently catalyzed by dirhodium(II) caprolactamate with tert-butyl hydroperoxide (
Copper-catalyzed aerobic oxidation of N-substituted hydroxylamines: Efficient and practical access to nitroso compounds
Frazier, Charles P.,Bugarin, Alejandro,Engelking, Jarred R.,Read De Alaniz, Javier
experimental part, p. 3620 - 3623 (2012/09/08)
A general and efficient aerobic oxidation of N-substituted hydroxylamines is described. The mild reaction conditions employed provide a catalytic and sustainable alternative to stoichiometric oxidation methods to gain access to a range of nitroso compound
Efficient cleavage of the N-O bond of 3,6-dihydro-1,2-oxazines mediated by some α-hetero substituted carbonyl compounds in mild conditions
Galvani, Gilles,Calvet, Geraldine,Blanchard, Nicolas,Kouklovsky, Cyrille
scheme or table, p. 1063 - 1070 (2009/02/05)
The efficient cleavage of the N-O bond of some nitroso Diels-Alder cycloadducts has been achieved in mild conditions, mediated either by 2,2-dimethyl-1,3-dioxan-5-one or 1,3-dithiolane-2-carboxaldehyde. These new and purely organic conditions allow an exc