110615-04-8

Basic information

• Product Name: (4-acetoxyphenyl)acetaldehyde
• Synonyms: (4-acetoxyphenyl)acetaldehyde
• CAS NO: 110615-04-8
• Molecular Weight: 178.188
• Mol File: 110615-04-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (4-acetoxyphenyl)acetaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (4-acetoxyphenyl)acetaldehyde(110615-04-8)
• EPA Substance Registry System: (4-acetoxyphenyl)acetaldehyde(110615-04-8)

Safety Data

• Hazardous Substances Data: 110615-04-8(Hazardous Substances Data)

Upstream product

• 60037-43-6 2-(4-acetoxyphenyl)ethanol 
• 2628-16-2 p-acetoxystyrene 

Relevant articles and documents

Maleimide-assisted anti-Markovnikov Wacker-type oxidation of vinylarenes using molecular oxygen as a terminal oxidant

Arylacetaldehydes were successfully synthesized by the anti-Markovnikov Wacker-type oxidation of vinylarenes using 1 atm O2 as a terminal oxidant under mild conditions. Electron-deficient alkenes, such as maleic anhydride and maleimides, were effective additives and would operate as ligands to stabilize the Pd(0) species during the reaction.

Oxidation of styrene and of some derivatives with H2O 2 catalyzed by novel imidazolium-containing manganese porphyrins: A mechanistic and thermodynamic interpretation

The oxidation of styrene and derivatives with H2O2 catalyzed by manganese porphyrins in acetonitrile is described. The effect of the imidazolium substituent on the catalytic efficiency has been also considered. The thermodynamic analysis has indicated that enthalpy rules styrene oxidation when catalysts Mn(Porph)-1 and Mn(Porph)-2 are used whereas the entropy is the driven force for Mn(Porph)-3 and Mn(Porph)-4 catalyzed reactions. Interestingly, an enthalpy-entropy compensation phenomenon is observed when comparing the thermodynamic results obtained for catalysts Mn(Porph)-3 and Mn(Porph)-4. Hammett plots for the studied manganese porphyrins provided small ρ-values, and this is typical for multi-step reactions, indicating that there is no significant charge separation in the transition state. For Mn(Porph)-1 and Mn(Porph)-2 the formation of multiple active species can be put forward whereas for Mn(Porph)-3 and Mn(Porph)-4 a concerted-type mechanism, via metalloxetane intermediate, fits well with the values obtained for those catalysts. The imidazolium-based catalysts have shown to be efficient catalysts in styrene and derivatives oxidation with hydrogen peroxide.