1107635-26-6

Basic information

• Product Name: tert-butyl 2-cyano-5-oxo-2-phenylheptanoate
• Synonyms: tert-butyl 2-cyano-5-oxo-2-phenylheptanoate
• CAS NO: 1107635-26-6
• Molecular Weight: 301.386
• Mol File: 1107635-26-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-butyl 2-cyano-5-oxo-2-phenylheptanoate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 2-cyano-5-oxo-2-phenylheptanoate(1107635-26-6)
• EPA Substance Registry System: tert-butyl 2-cyano-5-oxo-2-phenylheptanoate(1107635-26-6)

Safety Data

• Hazardous Substances Data: 1107635-26-6(Hazardous Substances Data)

Upstream product

• 1629-58-9 4-penten-3-one 
• 115549-32-1 2-t-butoxycarbonyl-2-phenylacetonitrile 

Relevant articles and documents

Enantioselective bimetallic catalysis of michael additions forming quaternary stereocenters

Robotlike: Low catalyst loadings of a planar-chiral ferrocenyl bispalladacycle are sufficient to catalyze the Michael addition of trisubstituted α-cyanoacetates to enones with excellent yields (TONs up to 2450) and high enantioselectivity. The reaction proceeds by a cooperative bimetallic mechanism and is superior to previous methods relying on soft Lewis acid catalysts. (Chemical Equation Presented)